Relative retention, Selectivity

Selectivity

Selectivity calculates the alpha value for all signal peaks except the first one. For every pair of adjacent peaks (peaks 1 and 2, tR of peak 1 < tR of peak 2), the selectivity is calculated as follows:

where

k'(x)

capacity factor for peak x: (tRx-t0)/t0

Relative Retention (EP)

RRT (EP) can be calculated only if an RRT reference peak has been defined and identified. Alpha values are < 1 if the peak is to the left of the RRT reference, and > 1 if the peak is to the right of the RRT reference.